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Study of Calixarenes, V. Friedel-Crafts Reaction of Calixarenes (1994)

Huang, Zhi-Tang ; Wang, Guo-Qiang

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 127 (1994), S. 519-523

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ISSN: 0009-2940

Keywords: Calixarenes ; Friedel-Crafts reaction ; selective ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The para-acylation of calix[4]arene (2), calix[6]arene (3), and calix[8]arene (4) by Friedel-Crafts reaction with a wide variety of acyl chlorides leads to 5-7 in moderate to good yields. Friedel-Crafts reaction of 26,28-dimethoxycalix[4]arene (8) gave products 9 selectively disubstituted in the para-positions of phenol rings.

Additional Material: 4 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19941270310

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