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(Bicyclo[3.2.0]hepta-1,3-dienyl)cobalt(I) Complexes (1993)

Angermund, Klaus P. ; Betz, Peter ; Butenschön, Holger

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 126 (1993), S. 713-724

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ISSN: 0009-2940

Keywords: Bicyclo[3.2.0]hepta-1,3-dienyl complexes ; Calculations, semiempirical ; Alkyne trimerization ; Cobalt complexes ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Three isomeric bicyclo[3.2.0]heptadienes 1 - 3 are compared by semiempirical calculations. Experimental attempts directed to the synthesis of derivatives of 1 are described. The synthesis, properties and some reactions of (η51-bicyclo[3.2.0]hepta-1,3-dienyl)(η41-cycloocta-1,5-diene)cobalt(I) (22), including an X-ray crystal structure determination of the reaction product with diphenylethyne, the tetraphenylcyclobutadiene complex 30, are presented.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19931260323

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