ISSN:
0009-2940
Keywords:
1,1′-Binaphthyls
;
Diphosphanes
;
Nickel complexes
;
Palladium complexes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
16- and 18-membered diphospha macrocycles (8, 12, and 15) have been synthesized from the corresponding 1,1′-binaphthyl precursors (6, 11, and 14, resp.) and o-phenylenebis(phenylphosphane) by means of high-dilution conditions in 55, 49, and 87% yield. X-ray structure analyses of 8a, 8b, 12b, and 12b · NiCl2 reveal their distinctly different conformations and conformational changes caused by complexation. These structural features are reflected in the pronounced different tendency of the compounds concerned to form Ni(II) and Pd(II) complexes.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19921250323