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Durch Verklammerung gespannte Perylene - Das Coronen-Isomer Dicyclopenta[1,2,3-cd:1′,2′,3′-Im]perylen und Dimethanoperylen (1991)

Jaworek, Wilfried ; Vögtle, Fritz

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 347-352

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ISSN: 0009-2940

Keywords: Aromaticity ; Methanonaphthalene ; Perylenes ; Polycycles ; Strained Hydrocarbons ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Strained Perylenes By Clamping - The Coronene Isomer Dicyclopenta[1,2,3,-cd: 1′,2′,3′-Im]perylene and DimethanoperylenePerylene (3) is clamped by C2 and C1 bridges with formation of the heptacyclic title compound dicyclopenta[1,2,3-cd: 1′,2′,3′-Im]perylene (10) (characterized) and 1H,6H-dicyclobuta[1,2,3-cd: 1′,2′,3′-Im]perylene (4) (detected by mass spectrometry and 1H-NMR absorptions). The influence of strain on UV and fluorescence spectra and on cyclic voltammetry is discussed

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19911240216

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