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Übergangsmetall-Silyl-Komplexe, 35. Silber(I)-Silyl-Komplexe (R3P)nAgSiR'3 (n = 1-3) (1990)

Wagner, Herbert ; Schubert, Ulrich

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 123 (1990), S. 2101-2107

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ISSN: 0009-2940

Keywords: Silver Complexes ; Silyl Ligands ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Transition-Metal Silyl Complexes, 35. - Silyl Complexes of Silver(I). (R3P)nAgSiR3' (n = 1-3)The complexes (R3P)nAgSiR'3 (n = 1-3), dppm(AgSiR'3)2 and dppe(AgSiR'3)2 [SiR3 = Si(aryl)3 or, except for n = 3, Si(Si— Me3)3) are prepared from the corresponding halide complexes or dppm/dppe(AgNO3)2 with LiSiR'3. The stability of the products increases with increasing n : the dppe- or dppm-substituted complexes are distinctly more stable than the corresponding complexes with monodentate phosphane ligands. The silver-silicon bond is highly polar as demonstrated by their properties.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19901231104

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