ISSN:
0009-2940
Keywords:
(Cyclopentadienyl)thallium(I) complexes
;
(Tetramethylcyclopentadienyl)metal complexes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
[(Dimethylphenylsilyl)tetramethylcyclopentadienyl]thallium(I) and [(Benzyldimethylsilyl)tetramethylcyclopentadienyl]-thallium(1) - Polymeric Organometallic Compounds with Chain Structure(Dimethylphenylsilyl)tetramethylcyclopentadiene (2) and (benzyldimethylsilyl)tetramethylcyclopentadiene (3) were prepared from (tetramethylcyclopentadienyl)lithium (1) and chlorodimethylphenylsilane or benzylchlorodimethylsilane, respectively. 2 and 3 react with TIOC2H5 (4) to form [C5Me4(SiMe2Ph))TI (5) and [C5Me4(SiMe2CH2Ph)]TI (6), respectively. The 1H- and 13C-NMR spectra of the new compounds as well as the single-crystal X-ray structural analyses of the polymeric metallocenes 5 and 6 are described and discussed.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19901230909