ISSN:
0009-2940
Keywords:
Sulphur-nitrogen ring
;
Titanium
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Adduct of a Five-Membered Trisulfurdinitrogen Dioxide Ring with Titanium TetrachlorideReaction of S6N4O4 with TiCl4 lead to [(S3N2O2)TiCl4]2 (2). Single crystals of 2 were obtained by recrystallization from liquid SO2. 2 forms chains of five-membered S3N2O2 rings connected by Ti2Cl8 units. The S2N2 part of the five-membered ring may be described as a 6-π electron system.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19901230623