ISSN:
0009-2940
Keywords:
Disilanes / Spiro[1,2-disilaindan-1,1′(2′H)-[1]silacyclobutene] derivative
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Silicon Compounds with Strong Intramolecular Steric Interactions, 39. - A Spirocyclic Silane from a 2.2-DimesityldisilaneTreatment of 1,1-Di-tert-butyl-1,2-dichloro-2,2-dimesityldisilane (3) with lithium tert-butylamide gives the spirocyclic silane 5 by a twofold intramolecular ring formation reaction. The X-ray structure analysis of 5 reveals strong deviations from the idealized tetrahedral geometry at the spirocyclic silicon atom.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19901230424