ISSN:
0009-2940
Keywords:
Metallaheterocycles
;
Niobium heterocycles
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Synthesis and X-ray Structure of a Nine-Membered Heterocycle Containing Niobium and Oxidic and Nitridic Structural Elements(Me3SiN—PPh2CH2)2 (1) reacts with NbCl5 to form (H2C—PPh2=NNbCl4)2 (2). The reaction of 2 with THF yields the nine-membered metallaheterocycle (3). Simultaneously, (ClCH2CH2)2 is produced. The X-ray structure of 3 is reported.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19891220907