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Abfangreaktionen für unbeständige [1-Chlor-2,2,2-trifluor-1-(trifluormethyl)ethyl]dialkylphosphite (1988)

Heine, Joachim ; Röschenthaler, Gerd-Volker

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 121 (1988), S. 379-381

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ISSN: 0009-2940

Keywords: Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Trapping Reactions for Unstable [1-Chloro-2,2,2-trifluoro-1-(trifluoromethyl)ethyl] Dialkyl PhosphitesThe reaction of ClP(OR)2 1a-d (R = Me, Et; R-R = CH2CH2, CMe2CMe2) with hexafluoroacetone yields the thermally unstable phosphites ClC(CF3)2OP(OR)2 4a-d besides other products. Trimethyl phosphite converts 4a-d into the phosphates (MeO)2P(O)OC(CF3)2P(OR)2 (R = Me, Et) 5a and b and the phosphonates (MeO)2P(O)C(CF3)2OP(OR)2 (R-R = CH2CH2, CMe2CMe2) 5c and d, Compounds formed in an Arbuzov reaction.

Additional Material: 3 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19881210228

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