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Vinylcarbanionen, 13. Einfache Synthese von Oxalessigsäure-Derivaten (1982)

Schmidt, Richard R. ; Talbiersky, Jörg ; Betz, Rainer

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 115 (1982), S. 2674-2678

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ISSN: 0009-2940

Keywords: Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Vinyl Carbanions, 13. Convenient Synthesis of Oxaloacetic Acid DerivativesThe vinyllithium derivatives 2a, b and 9a, b, obtained by direct lithiation of the functionally substituted acrylic acid derivatives 1a, b and 8a, b, respectively, react with heterocumulenes A-E such as phenyl isocyanate, phenyl isothiocyanate, and carbon dioxide to give derivatives of oxaloacetic acid. In a single step reaction the oxaloacetic acid monoester 6a and monoamide 6b were synthesized.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19821150731

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