ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Reaction of Complex Ligands, XXI1) Competing Olefin Scission and Cyclopropanation of Enamines in the Reaction with Carbene ComplexesPentacarbonyl(methoxyphenylcarbene)chromium (1) reacts with 1-phenyl-1-piperidinoethene (2) to give both 1-methoxy-1,2-diphenyl-2-piperidinocyclopropane (3) and pentacarbonyl(phenyl-piperidinocarbene)chromium (4. The reaction of 1 with 1-pyrrolidino-1-cyclopentene (5) leads to insertion of the alkene into the metal carbene bond with formation of 6.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19811140538