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Zur Reaktion von Pinenen mit Chlorwasserstoff (1979)

Weigand, Eckehard F. ; Schneider, Hans-Jörg

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 112 (1979), S. 3031-3033

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ISSN: 0009-2940

Keywords: Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: On the Reaction of Hydrogen Chloride with Pinenessyn-Addition of DCI to the less hindered site of α- and β-pinene (1, 2) is demonstrated by a combination of 13C- and 2H-NMR spectroscopy. The resulting tertiary chloride is configurationally pure and isomerizes to bornyl chloride only. The rapidity of the isomerization with the possible conversion of a tertiary to a secondary carbocation is rationalized by strain calculations with a molecular mechanics force field.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19791120826

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