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Übergangsmetall-Carbin-Komplexe, XLIII: Reduktion einer Metall-Kohlenstoff-Dreifachbindung (1978)

Fischer, Ernst Otto ; Frank, Albin

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 111 (1978), S. 3740-3744

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ISSN: 0009-2940

Keywords: Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Transition Metal Carbyne Complexes, XLIII: Reduction of a Metal-Carbon Triple BondReaction of [π-C5H5(CO)2ReCC6H5]+[BCl4]- with Et2AlH yields - depending on reaction conditions - the novel secondary carbene complex π-C5H5(CO)2ReCHC6H5 (2) or the σ-benzylhydrido complex π-C5H5(CO)2HReCH2C6H5 (3). The reaction is the first example of a stepwise reduction of a metal-carbon triple bond to a single bond.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19781111119

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