ISSN:
0947-6539
Keywords:
arsenic
;
cobalt
;
density functional calculations
;
structural elucidation
;
Zintl anions
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
[As7(SiMe3)3] reacts with [(Cp*CoCl)2] to give black crystals of the ionic compound [(Cp*Co)3As6][CoCl4] (1). The cation [(Cp*Co)3As6]2+ consists of an As6 prism, with squares capped by [Cp*Co] fragments. When [(CptBuCoCl)2] is used instead of [(Cp*CoCl)2] in the reaction, dark red crystals of [(CptBuCo)3As6][CoCl3(thf)]2 (2) and green-black crystals of [(CptBuCo)2As4][Co3Cl8(thf)2] (3) can be obtained. The cation in 2 shows a structure very similar to that of 1. The [(CptBuCo)2As4]2+ cations in 3 can be described as a triple-decker sandwich complex with two [CptBuCo]+ fragments bridged by an As4 ligand. Density functional calculations reproduce the experimental data of 1 and 3 and allow an interpretation of molecular electronic structure and bonding in these and related compounds with As replaced by P and Co by Fe.
Additional Material:
10 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/chem.19970030917
