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Chlorinated high density polyethylene. I. Chain characterization (1988)

Chang, B. H. ; Zeigler, R. ; Hiltner, A.

Stamford, Conn. [u.a.] : Wiley-Blackwell

Polymer Engineering and Science 28 (1988), S. 1167-1172

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ISSN: 0032-3888

Keywords: Chemistry ; Chemical Engineering

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics

Notes: High density polyethylene has been chlorinated by three different methods: in suspension and in solutions of two different solvents. Carbon-13 NMR and infrared analysis show that chlorination in chlorobenzene solution leads to statistically random distribution while chlorination in suspension gives highly blocky substitution. An intermediate distribution was obtained by chlorination in tetrachloroethane solution.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pen.760281806

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