ISSN:
0032-3888
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Our laboratory recently published several analytical equations that can be used to predict the melting rate of fully compacted solid polymers sliding on a heated metal surface, modeling the melting mechanism inside an extruder. These equations were obtained by seeking asymptotic solutions to the differential equations describing the melting mechanism, temperature, and shear-dependent viscosity of polymer melts. Following the same asymptotic approach, we successfully developed accompanying analytical equations for predicting the stress required to slide fully compacted solid polymers on a heated metal surface. The accuracy of these analytical stress equations was found to be reasonable, although not fully satisfactory, by comparing their predictions to the experimentally measured values. The accuracy of the stress calculation is directly related to the accuracy of the viscosity values at high shear rates. The consideration of the temperature and shear dependencies of melt viscosity is most important for accurate prediction of the stress, just as it is for the melting rate. The stress not only depends on the melt rheological properties of the polymer but also on the thermodynamic properties.
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pen.760230405
