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Determination of eigenvectors in DNA polymer spectroscopy by isotopic substitution (1990)

Van Zandt, L. L. ; Saxena, V. K.

New York : Wiley-Blackwell

Biopolymers 30 (1990), S. 87-91

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ISSN: 0006-3525

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: A simple relationship between frequency shifts to be expected in molecular vibrational spectra upon isotopic substitution and component values of eigenvectors is displayed. Application of this expression to the problem of force constant refinement is discussed in terms of a refinement algorithm developed some years ago to overcome particular problems associated with large molecular systems. Calculations of expected isotopic shifts have been calculated and are tabulated here for experimental reference.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/bip.360300110

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