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  • 1
    Electronic Resource
    Electronic Resource
    Computation of phase and chemical equilibrium: Part I. Local and constrained minima in Gibbs free energy (1979)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 25 (1979), S. 991-999 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Several methods are reviewed for determining compositions in multiphase, reacting mixtures at equilibrium. Wolfe's quadratic programming algorithm is applied and results compared with the Rand method (Dluzniewski and Adler 1972), NASA method (Gordon and McBride 1971) and the George et al. (1976) implementation of Powell's method. For poor guesses in compositions, local and constrained minima in Gibbs free energy may arise, giving incorrect phase distributions.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690250610
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