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The experimental determination of the volumetric properties and virial coefficients of the methane-ethylene system (1969)

McMath, H. G. ; Edmister, W. C.

Hoboken, NJ : Wiley-Blackwell

AIChE Journal 15 (1969), S. 370-378

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ISSN: 0001-1541

Keywords: Chemistry ; Chemical Engineering

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology

Notes: An apparatus was constructed for making isochoric measurements of P-V-T properties. Experimental compressibility factors were obtained and are presented for methane, ethylene, and four intermediate mixtures at 60, 40, and 20°F., with pressures from 260 to 2,220 lb./sq.in.abs. Second and third virial coefficients and interaction virial coefficients were determined from the data. The compressibility factors and the virial coefficients are compared with the Benedict-Webb-Rubin equation of state, applied in its original form and in a recent generalized form.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/aic.690150314

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