ISSN:
0001-1541
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Process Engineering, Biotechnology, Nutrition Technology
Notes:
Three viscosity correlations were tested for liquids at their boiling points. Compounds studied included normal paraffins, branched-chain hydrocarbons, aromatics, halogenated methanes and ethanes, water, and aliphatic alcohols. The correlations were tested for the most part with viscosity and thermodynamic data found in the literature. Some experimental viscosity measurements were made, however, for normal paraffins from pentane to octane at temperatures up to about 300°F., which is higher than has previously been reported.Two correlations are based on Eyring's theory of absolute reaction rates. The third is based on the compressibility factor of the saturated liquid, and this correlation is unique, as all available data for normal paraffins with eight or more carbon atoms are represented by a single curve. The three correlations presented here can be used to extrapolate viscosity data over large temperature ranges up to the critical temperature. Logical predictions of the viscosities of related compounds are possible.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aic.690020304
