ISSN:
0930-7516
Schlagwort(e):
Chemistry
;
Industrial Chemistry and Chemical Engineering
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
,
Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
Notizen:
The Cocurrent Downflow Contactor (CDC) has been developed as a mass transfer and reactor device, with and without addition of tangential (swirl) flow, giving gas hold-up (Eg) values of 0.5-0.75, interfacial areas in the range 1000-6000 m2m-3 liquid and kLa values in the range of 0.15-1.55 s-1 for absorption using the O2/H2O system. It has been studied as a catalytic slurry reactor for the hydrogenation of (i) itaconic acid and (ii) triglycerides catalysed by Pd and Ni catalysts. The reactions were observed to be largely surface-reaction rate controlled, due to the very efficient mass transfer (kLa up to 11.75 s-1 under reaction conditions) and application of swirl flow-enhanced reaction rates. The CDC has recently been found to be capable of operating as a fixed bed reactor, thus eliminating a downstream catalyst separation problem (therefore more cost effective), and is superior in its mass transfer characteristics to other known devices. Scale-up can be undertaken without loss of performance efficiency.
Zusätzliches Material:
10 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/ceat.270170504
