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Correlation between 27Al and 71Ga NMR chemical shifts (1993)

Bradley, Susan M. ; Howe, Russell F. ; Kydd, Ronald A.

Chichester : Wiley-Blackwell

Organic Magnetic Resonance 31 (1993), S. 883-886

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ISSN: 0749-1581

Keywords: Aluminum-27 ; Gallium-71 ; Aluminosilicates ; Aluminophosphates ; Aluminas ; Gallosilicates ; Gallophosphates ; Gallias ; Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: A linear relationship has been found to exist between the aluminum-27 and gallium-71 NMR chemical shifts of a series of structurally analogous aluminum and gallium compounds having only oxygen in the first metal coordination spheres; δ71Ga = 2.83(δ27Al) - 4.50. This relationship allows the prediction of 71Ga chemical shifts for such gallium compounds from the 27Al values already known for their aluminum analogues, and also a greater understanding of observed 71Ga chemical shifts.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/mrc.1260311002

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