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A set of alkyl substituent constants for correlating chemical shifts of a variety of nuclei (1986)

Poh, Bo-Long

Chichester : Wiley-Blackwell

Organic Magnetic Resonance 24 (1986), S. 816-820

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ISSN: 0749-1581

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: A set of substituent constants for alkyl groups has been calculated and shown to be useful in the correlations of chemical shifts of atoms that have a directly bonded alkyl group(s). The correlation equation used is δ(X) = mσn + b, where δ(X) is the chemical shift of atom.X, δ. is the alkyl substituent constant and m and b are constants for a given series of compounds. Forty-two series of compounds, consisting of thirteen different X nuclei (13C, 14N, 15N, 17O, 19F, 29Si, 31P, 35CI, 75As, 77Se, 113Cd, 125Te, 199Hg) have been correlated.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/mrc.1260240916

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