ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Unusual expulsion of ‘SO’ was observed from the molecular ions of substituted diphenyldithiocarbonates under electron impact conditions. An initial aryloxy migration to sulphur followed by further rearrangement is proposed for this process, based on the substituent effects. The diarylthioketone radical-cation structure assigned for the [M - SO] ion was confirmed through the collision-activated dissociation B/E linked-scan spectra.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210280433