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Charge neutralization of ions from benzene (1988)

Sedgwick, J. B. ; Nelson, P. R. ; Steiner, P. A. ; [et al.]

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 23 (1988), S. 256-260

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ISSN: 0030-493X

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Cross-sections have been measured for the charge neutrilization if ions from benzene in kiloelectron-volt collisions with benezene target molecules. Measured values range from 65 Å2 for the symmetric [C6H6]+—C6H6 resonant reactions to 8 Å2 for [C3H3]+—C6H6 reactions. Cross-sections computed using a simple resonance charge transfer model compare favourably with experimental data for the symmetric reactions. The cross-sections for asymmetric reactions are smaller that those for they symmetric system and magnitudes of the asymmetric cross-sections are correlated with recombination energies of the respective ions.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/oms.1210230407

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