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Rearrangements in the electron impact induced fragmentations of sulfonyl chlorides (1977)

Davis, Paul P. ; Grossert, J. Stuart ; Langler, Richard F. ; [et al.]

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 12 (1977), S. 659-662

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ISSN: 0030-493X

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The major fragmentation pattern obsrved in the mass spectra of simple alkane- and arylsulfonyl chlorides may be rationalized by loss of a chlorine atom from the molecular ion, followed by loss of SO2 with concomitant carbocation formation. The mass spectra of α-mesyl sulfonyl chlorides and napthalenesulfonyl chlorides exhibit ions resulting from chlorine atom migration to the α-carbon atom with concomitant loss of SO2. The mass spectra of α-mesyl sulfonyl chlorides also show ions which involve chlorine atom migration to the β-sulfonyl group.

Additional Material: 5 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/oms.1210121102

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