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Field desorption mass spectra of stereoisomeric glycosides (1973)

Lehmann, W. D. ; Schulten, H.-R. ; Beckey, H. D.

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 7 (1973), S. 1103-1108

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ISSN: 0030-493X

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Field desorption mass spectrometry (FD-MS) yields differentiated spectra for unshielded α- and β-stereoisomeric glycosides. The small but characteristic differences enable a distinction to be made between the two isomers. Valuable structural information can be deduced from the simple cleavage between the sugar moiety of the molecule and the aglycon. A short comparison with electron-impact (EI) and field ionisation (FI) spectra is given.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/oms.1210070911

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