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Carbon-13 chemical shifts of substituted nortricyclenes (1973)

Lippmaa, E. ; Pehk, T. ; Paasivirta, J.

Chichester : Wiley-Blackwell

Organic Magnetic Resonance 5 (1973), S. 277-283

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ISSN: 0030-4921

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: 13C NMR spectra of a series of substituted nortricyclene derivatives have been measured, and the 13C chemical shifts interpreted in terms of α, β, γ and δ-effects. The nature of these substiuent shifts is discussed together with some analytical possibilities. The substituent shifts provide valuable data about the steric effects in strained molecules and can be used as increments for structural analysis, particularly for the determination of orientations of substituent groups.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/mrc.1270050607

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