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The use of chiral solvents to distinguish meso from d or 1 diastereoisomers (1973)

Abraham, R. J. ; Siverns, T. M.

Chichester : Wiley-Blackwell

Organic Magnetic Resonance 5 (1973), S. 253-254

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ISSN: 0030-4921

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The 56·4 MHz 19F spectrum of a mixture of meso and dl 1,2-difluoro-1,2 dichloroethane in L-bornyl acetate resolved the 19F resonances of the separate d and l stereoisomers, thus identifying the dl spectrum, but not those of the meso isomer.These observations are considered with other examples of the use of chiral solvents to distinguish meso and dl isomers.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/mrc.1270050513

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