ISSN:
0377-0486
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The use of the transform method was extended so as to permit the treatment of the resonance Raman effect with the participation of two interfering electronic transitions. The relevant equations were tested in the model system [Ru(bipy)2(violurate)]PF6, the Raman excitation profiles of which show clearly the presence of two chromophoric moieties. The present results strongly suggest that the two relevant excited states participate by means of Albrecht's A terms, whereas the vibronic coupling by the B term is not decisive. The independence of the two chromophoric moieties is reflected in distinct displacements of the respective potential minima.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jrs.1250240708