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A new multichannel Raman optical activity instrument (1987)

Barron, L. D. ; Torrance, J. F. ; Cutler, D. J.

Chichester [u.a.] : Wiley-Blackwell

Journal of Raman Spectroscopy 18 (1987), S. 281-287

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ISSN: 0377-0486

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: A fully computer-controlled Raman optical activity spectrometer equipped with an intensified diode array detector is described. Despite using a conventional single-lens light collection system for simplicity, both polarized and depolarized Raman optical activity spectra can be obtained rapidly and routinely. A novel double grating spectrograph design permits good spectra to be obtained down to 50 cm-1 in liquids. Natural spectra of the chiral samples (-)-α-pinene and (+)-methylcyclohexanone and magnetic spectra of iridium (IV) hexachloride are presented.

Additional Material: 7 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jrs.1250180410

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