ISSN:
0951-4198
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Physics
Notes:
The energetics of S2+· ion formation in electron dissociative ionization of linear CS2 are investigated experimentally with a crossed-beam apparatus. Ab initio self-consistent-field molecular orbital (SCF MO) calculations of potential energy curves for low-lying electronic states of this ion have been made in order to explain how stable S2+· ions are formed, initially at the very large internuclear separation of 3.2 Å.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/rcm.1290030204