ISSN:
0935-6304
Keywords:
Capillary gas chromatography (CGC)
;
Temperature programmed CGC
;
Analysis of volatiles
;
Multicomponent separation optimization
;
Simplex optimization
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The modified simplex algorithm proposed by Nelder and Mead has been used to optimize the separation by temperature programmed capillary GC, of volatile compounds present in alcoholic beverages. An adequate objective function, CRF, based on the separation factor of Kaiser has been used for the optimization process.A factorial design was initially performed to verify the relationship between the several parameters of interest. Following this, the optimization was executed and a surface adjusted within the set of experimental data.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jhrc.1240140611
