ISSN:
0935-6304
Keywords:
Capillary columns
;
Glass
;
Fused silica
;
Acid leaching
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A study was carried out on the effects of acid leaching of capillary column wall materials. Leaching experiments with glass and fused silica were performed under static and dynamic conditions; moreover, the influence of the temperature was investigated. The amount of water released during different temperature programs was measured with a microwave plasma detector. Different leaching conditions and column wall materials cause considerable variations in water production. These results probably explain the disappointing deactivation efficiency obtained for fused silica and dynamically leached soft glass if HMDS is used. Evidence was found for an increase in surface area due to acid leaching.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jhrc.1240081103
