Publication Date:
2012-02-03
Description:
The Azores archipelago is made of nine islands all of volcanic origin and a few
islets located in the North Atlantic Ocean, about 1800 km west of Portuguese
mainland at the triple junction of the Eurasian, North American and Nubian plates
(Azores Triple Junction = ATJ). Graciosa Island is part of the Central Group of
Azores archipelago and is located on the Terceira Rift, a major tectonic feature of
the ATJ. The main hydrothermal manifestations at Graciosa Island occur in the
Caldeira volcano (SE part of the island), and particularly inside the huge (150 m
wide, 80 m high) Furna do Enxofre lava cave located in the Caldeira, where a
bubbling mud pool releases steam and gases, leading to the accumulation of CO2
at the bottom of the cave, filled by a coldwater subterranean lake. Three field work
campaigns were carried out at Graciosa Island and 14 water samples have been
collected, from boreholes, springs and the subterranean lake for isotopic (18O, 2H
and 3H) and chemical analysis. The groundwater samples were plotted along the
GMWL, and two water groups were identified in the 18O vs. 2H diagram. The
splitting up of the samples is even more visible when the O-18 content is plotted
as a function of the temperature or as a function of the electrical conductivity.
Besides the differences in mineralization and temperature observed in the groundwater
samples from Graciosa Island, an isotopic shift towards more enriched
values is also observed. The salinity and isotopic content seems to indicate not a
simple mixture between two end-members, i.e. seawater – fresh water: another
process of mineralization and isotope enrichment must be considered in this active
volcanic environment. A hypothesis to be formulated is that the source of salts
could be associated to mixing with boiling seawater, that by evaporation will be
able to: i) increase groundwater salinity, ii) strongly change the 2H content to more
enriched values, and iii) absent or limited variation in d18O content.
Description:
Published
Description:
Budapest, Hungary
Description:
4.5. Studi sul degassamento naturale e sui gas petroliferi
Description:
restricted
Keywords:
Water isotope
;
Graziosa Island
;
03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters
;
03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
;
04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
Repository Name:
Istituto Nazionale di Geofisica e Vulcanologia (INGV)
Type:
Oral presentation
