ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
We report frequency-dependent dipole and quadrupole polarizabilities of the oxygen molecule in its 3Σ−g ground state. These properties are obtained by means of the multiconfiguration self-consistent field method and used for the computation of the van der Waals coefficients of (O2)2 and the O2–Rg dimers, where Rg is He, Ne, Ar, and Kr. The required frequency-dependent polarizabilities of the rare gases were computed earlier by means of second-order many body perturbation theory.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.467256