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Comment on "A study of HeI photoelectron spectroscopy on the electronic structure of the nitrate free radical NO3" [J. Chem. Phys. 106, 3003 (1997)] (1998)

Monks, P. S. ; Stief, L. J.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 108 (1998), S. 1292-1292

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The recent photoelectron spectroscopy (PES) paper by Wang, et al. confirms our earlier photoionization mass spectrometric (PIMS) determination of the adiabatic ionization energy of NO3. The PES results are also consistent with our conclusion that the ground-state neutral geometry for NO3 is D3h. However, the PE spectrum shows a second band (and higher bands) with a vertical I.E. (ionization energy) at 13.18 eV that was absent in our photoionization efficiency spectrum. A possible reason for the apparent discrepancy is suggested and further differences between the two studies are discussed. © 1998 American Institute of Physics.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.475492

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