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XAFS analysis of triiodide ion in solutions (2001)

Sakane, Hideto ; Mitsui, Takayuki ; Tanida, Hajime ; [et al.]

Chester : International Union of Crystallography (IUCr)

Journal of synchrotron radiation 8 (2001), S. 674-676

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ISSN: 1600-5775

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Geosciences , Physics

Notes: Iodine K-edge XAFS of triiodide ions in various solvents were measured at SPring-8 BL01B1 and analyzed. Though the anion takes a linear and symmetric form, the second peak expected from enhanced multiple scatterings can be hardly observed because of its large vibrations. The bond distances and the Debye-Waller factors for the I-I couple vary when protic solvents were used. It was indicated that the larger the Mayers' acceptor number of the solvent is, the larger the Debye-Waller factor is. It was also found that among the aprotic solvents, the larger the Gutmann's donor number is, the smaller the Debye-Waller factor is.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S0909049500017179

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