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  • 1
    Electronic Resource
    Electronic Resource
    The thermal decomposition of peroxyacetic nitric anhydride (PAN) and peroxymethacrylic nitric anhydride (MPAN) (1992)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 24 (1992), S. 297-307 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The rate coefficients of thermal decomposition of peroxyacetic nitric anhydride (PAN) and peroxymethacrylic nitric anhydride (MPAN) were measured over the temperature range 302-323 K. The resulting Arrhenius expressions were k = 1017.4±0.4 exp(-28.5 ± 0.5/RT) for PAN, and k = 1016.2±0.7 exp(-26.8 ± 1.0/RT) for MPAN, where the activation energy is in Kcal/mol. These results are in good agreement with previous studies of PAN and other PAN-type compounds, and imply that energies of RC(O)OO—NO2 bonds are relatively independent of the nature of R.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550240307
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