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A dynamic method for the study of heterogeneous catalytic kinetics (1967)

Bennett, Carroll O.

Hoboken, NJ : Wiley-Blackwell

AIChE Journal 13 (1967), S. 890-895

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ISSN: 0001-1541

Keywords: Chemistry ; Chemical Engineering

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology

Notes: For a trial multistep mechanism for a heterogeneous catalytic reaction, it is suggested that dynamic experiments can be used to calculate the forward and reverse rate constants of individual steps. The experiments consist of the measurement of the composition of the effluent from a continuous stirred-tank catalytic reactor as a function of time as the input composition to the reactor is perturbed. The method of moments is used to obtain the kinetic constants for a trial mechanism from the experimental data.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/aic.690130515

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