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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 380 (1971), S. 56-64 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Crystals of PCl5NbCl5 and PCl5TaCl5 are isomorphous; space group P1. The structures are ionic, consisting of tetrahedral cations PCl4+ and octahedral anions NbCl6- and TaCl6-, respectively. Twinning is frequently observed in both compounds; an explanation thereof is given on the basis of the OD theorie.
    Notes: Die Röntgenstrukturanalyse der kristallisierten Verbindungen PCl5NbCl5 und PCl5TaCl5 ergab: beide Verbindungen sind isomorph und kristallisieren in der Raumgruppe P1. Die Verbindungen sind heteropolar aufgebaut und bestehen aus PCl4+-Kationen und den Anionen NbCl6- bzw. TaCl6-. Der Charakter ihrer Verzwillingung wird diskutiert.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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