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Form birefringence of crystalline polymers (1974)

Chang, C. ; Peiffer, D. ; Stein, Richard S.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Physics Edition 12 (1974), S. 1441-1456

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ISSN: 0098-1273

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The theory of Franklin et al. is employed for the calculation of the maximum form birefringence of a polymer having lamellar morphology. The results confirm the experimental conclusion that for low-density polyethylene, the form birefringence approaches 3% of the total birefringence. The theory also predicts the parabolic dependence of the form birefringence on the refractive index of the amorphous phase. It may be applied to estimate the dynamic form birefringence and leads to a value of the dynamic strain-optical coefficient which is of the order of 2-15% of the total.

Additional Material: 11 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1974.180120716

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