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Diffusion and chemical reaction in isobutylene hydration within cation exchange resin (1967)

Gupta, Vijai P. ; Douglas, W. J. M.

Hoboken, NJ : Wiley-Blackwell

AIChE Journal 13 (1967), S. 883-889

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ISSN: 0001-1541

Keywords: Chemistry ; Chemical Engineering

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology

Notes: The chemical reaction and diffusion rate parameters were determined for the hydration of liquid isobutylene to t-butanol with a cation exchange resin catalyst. High reaction rates were found to result from a high diffusivity of isobutylene within the resin catalyst. Both the high value for diffusivity and its negative temperature coefficient are consistent with the transport mechanism within the resin, being that of surface diffusion of isobutylene in an adsorbed state.

Additional Material: 9 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/aic.690130514

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