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Hexacoordinated carbon or tetracovalent silicon? (1998)

Schiemenz, G. P. ; Schiemenz, B. ; Petersen, S. ; [et al.]

New York, NY [u.a.] : Wiley-Blackwell

Chirality 10 (1998), S. 180-189

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ISSN: 0899-0042

Keywords: hypercoordinate silicon in naphthylsilanes ; X-ray structures ; NMR spectra ; reinterpretation ; Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Hexacoordinate silicon has been claimed to occur in bis(8-dimethylamino-naphth-1-yl)silanes on the basis of X-ray data and NMR spectra. Very much the same effects are shown by a bis(8-dimethylamino-naphth-1-yl)carbinol, pointing to essentially the same bonding in the Si and C compounds. Faced with the choice that either the carbon in the carbinol is hexacoordinate, too, or that the silicon in the silanes is, in fact, tetracovalent, we prefer the latter conclusion. Chirality 10:180-189, 1998. © 1998 Wiley-Liss, Inc.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/chir.28

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