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Synthese und Struktur von 3-IsochinolinolenHerrn Professor Dr. H. Bredereck in Dankbarkeit und Verehrung zum 70. Geburtstag gewidmet. (1974)

Simchen, Gerhard ; Häfner, Manfred

Weinheim : Wiley-Blackwell

Liebigs Annalen 1974 (1974), S. 1802-1815

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ISSN: 0075-4617

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Description / Table of Contents: Synthesis and Structure of 3-Isoquinolinols**)1-Halogeno-3-isoquinolinols 2-4 are prepared by cyclization of (2-cyanophenyl)acetyl chlorides 1 in presence of anhydrous hydrogen halides. Catalytic hydrogenation gives the 3-isoquinolinols 8. The lactam-lactim tautomerism of these compounds is discussed.

Notes: (2-Cyanphenyl)acetylchloride 1 cyclisieren in Gegenwart wasserfreier Halogenwasserstoffsäuren zu I-Halogen-3-isochinolinolen 2-4. Durch katalytische Hydrierung erhält man aus diesen die 3-Isochinolinole 8. Die Lactam-Lactim-Tautomerie dieser Verbindungsklassen wird untersucht.

Additional Material: 10 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jlac.197419741110

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