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  • 1
    Electronic Resource
    Electronic Resource
    Stereoselective Total Synthesis of a Novel D-Homosteroid by a Twofold Heck Reaction (2000)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 2000 (2000), S. 1827-1830 
    Details
    ISSN: 1434-193X
    Keywords: C-C coupling ; Homosteroids ; Palladium ; Steroids ; Total synthesis ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---The D-homosteroid 1 was synthesized by two successive Heck reactions starting from enantiopure 3 and the bromoarene 2 containing a (Z)-bromovinyl group. The first intermolecular Pd-catalyzed reaction leads to 6 in a highly regio- and diastereoselective way which forms 1 with an unusual cis-junction of the rings B and C by a second intramolecular Heck reaction.
    Type of Medium: Electronic Resource
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