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Synthesis of (Hemi)Carceplex Adsorbates for Self-Assembly on Gold (2000)

Huisman, Bart-Hendrik ; Rudkevich, Dmitry M. ; Farrán, Angeles ; [et al.]

Weinheim : Wiley-Blackwell

Liebigs Annalen 2000 (2000), S. 269-274

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ISSN: 1434-193X

Keywords: Cage compounds ; Calixarenes ; Cavitands ; Carcerands ; Gold ; Interfaces ; Monolayers ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: ---The synthesis of sulfide-functionalized (hemi)carceplexes suitable for self-assembly on gold is described. A noncentrosymmetrical carceplex 9 (guest DMF) was synthesized by the combination of calix[4]arene 4 and resorcin[4]arene 3, while a noncentrosymmetrical hemicarceplex 12 (guest NMP) was prepared by the combination of two different resorcin[4]arenes, 3 and 10. These adsorbates form ordered self-assembled monolayers on gold with their quasi C4v axis perpendicular to the surface. The two positions possible for the incarcerated guest lead to diastereotopic surfaces.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

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