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Benzyloxyfluorocarbene: Resistance to fragmentation (1990)

Moss, Robert A. ; Zdrojewski, Tadeusz

Chichester : Wiley-Blackwell

Journal of Physical Organic Chemistry 3 (1990), S. 694-696

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ISSN: 0894-3230

Keywords: Organic Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Benzyloxyfluorocarbene resists fragmentation to benzyl fluoride, and can be intercepted by water, fluoride ion, methanol or acrylonitrile. In contrast, benzyloxybromocarbene and benzyloxychlorocarbene fragment to the corresponding benzyl halides, and are not efficiently trapped.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/poc.610031012

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