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  • 1
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Journal of Physical Organic Chemistry 3 (1990), S. 567-574 
    ISSN: 0894-3230
    Keywords: Organic Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Unimolecular decomposition of 0·1 Torr of diethyl carbonate, diethyl-d5 carbonate and diethyl-d10 carbonate induced by irradiation with a CO2 TEA laser was investigated. In all cases only ethylene, ethanol and CO2 were obtained. In the case of diethyl-d5 carbonate, both ethylene-d4 and ethylene-d0 were observed together with the corresponding isotopic variants of ethanol. The chemical branching ratio was determined as a function of irradiation frequency and laser fluence by analysis of the ethylene-d0/ethylene-d4 ratio. RRKM theory applied to the branching ratio data requires very different average energies for two sets of fluence and frequency conditions that give identical total yields.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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